Furfural derivatives are tested as automotive fuel in blends with gasoline. Identification of the substancemixture and of the companyundertaking date issued 11. It is a product of the dehydration of sugars, as occur in a variety of agricultural byproducts, including corncobs, oat, wheat bran, and sawdust. A novel method for furfural recovery via gas stripping. Use explosionproof electricalventilatinglightingequipment.
Box 12233 research triangle park, nc 27709 june 2010. Material safety data sheet product name synonym material uses in case of emergency 1. The global furfural market demand was 300 kilotons in 20. A meta description is an html tag in the html code of your website, which allows you to customize a section of text that describes the page itself. It has an aldehyde group attached to the 2position of furan. Furfural is an aldehyde of furan and is a yellow oily liquid in pure form, but tends to turn brown upon prolonged exposure to air and moisture. It is a clear, colorless motile liquid having a characteristic almondbenzaldehyde odor. Production of furfural from xylose at atmospheric pressure. Firstaid measures general advice if symptoms persist, call a physician. An aldehyde is an organic functional group that has. The perfect blend of products and services that bring your creativity to life. Furfural definition is a liquid aldehyde c5h4o2 of penetrating odor that is usually made from plant materials and used especially in making furan or phenolic resins and as a solvent. The oral reference dose rfd is based on the assumption that thresholds exist for certain toxic effects such as cellular necrosis.
Substance name furfural casrn 98011 last revised 09071988. One reagent lane fair lawn, nj 07410 for information in north america, call. Furfuryl alcohol is an organic compound containing a furan substituted with a hydroxymethyl group. The strong shift towards the development of biobased chemicals on account of volatile petrochemical prices and growing environmental concerns is expected to remain a key driver for the growth of global furfural market. Fraga onepot production of furfuryl alcohol via xylose dehydration followed by furfural hydrogenation was investigated over a dual catalyst system composed of ptsio 2 and sulfated zro 2 as metal and acid catalysts, respectively.
Univar usa inc material safety data sheet for additional information contact msds coordinator during business hours, pacific time. The yields of furfural from the various runs as shown in table 2 were found to be identical with an average value of 4. Page 3 of 5 7 handling and storage precautions for safe handling. Opinion of the scientific panel on food additives, flavourings, processing aids and materials in contact with food afc related to flavouring group evaluation fge.
Not considered to be a fire hazard environmental precautions. It forms condensation products with many types of compounds, including phenol, amines and urea. Furfural c 4 h 3 ocho, also called 2furaldehyde, best known member of the furan family and the source of the other technically important furans. One of the main advantages of lignocellulosic biomass as f eedstock in furfural production is the fact that these. Available studies about furfural production from aqueous hemicelluloses solutions are sparse, being necessary more studies to prove the viability of using this material for furfural production 18. Furfural, a sister chemical to the increasingly popular hydroxymethylfurfural or hmf molecule, is regaining attention as a biobased alternative for the production of everything from antacids and fertilizers to plastics and paints. The first scientific opinion sccnfp082204 on furfural was adopted by the sccnfp during. Du pont abandons the furfuralthfadiponitrile process. There are 833 suppliers who sells furfural on, mainly located in asia. Furan has various interesting properties, such as it thermosets easily, has physical strength and exhibits resistance to corrosion.
The products were separated using a zorbax sbc18 column 3. The top countries of suppliers are india, china, and india, from which the percentage of furfural supply is 1%, 94%, and 1% respectively. An exothermic resinification of almost explosive violence can occur upon contact with strong mineral acids or alkalis. Furfural appears as colorless or reddishbrown mobile liquids with a penetrating odor. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. Ma te r i a l s a fe ty d a ta s h e e t f u r fu r a l. Furfural is an organic compound with the formula c 4 h 3 ocho.
Furfural is obtained by the hydrolysis of vegetable matter, such as corn stumps, rice offal, and other materials that contain pentosan. Buy high purity furfural analytical standards from chem service inc. It forms condensation products with many types of compounds. Moreover, even if the simulation does not permit a purge fraction lower than 3%, the real industrial case could tune this value and thus utilize lower fresh nitrogen flows. Dec 17, 2019 furfural countable and uncountable, plural furfurals organic chemistry a heterocyclic aldehyde derivative of furan. It is a colorless liquid, although commercial samples are often brown. Furfural is an important platform chemical with a wide range of applications. When fecl 3 was used only as catalyst without sulfuric acid added, the yield of furfural was very low 5% with 10% xylose for 5 h. Safety data sheet monoethanolamine mea page 1 of 7 material safety data sheet produced date. Atmospheric removal by wet deposition may be a significant. Secondaryproducts were also identified by gcms 6890 gc and 5973mass selective detector from agilent using a dbffap column, helium as carrier gas at 1 ml. As seen infigure 4b, the yield of furfural is 45% with 0.
A wide variety of furfural options are available to you, such as agriculture grade, industrial grade, and medicine grade. Material safety data sheet section 1 furfural 1 chemical product and company identification msds name. Furfural analytical standards 98011, n121021g chem. It is a colorless liquid, but aged samples appear amber. The name furfural comes from the latin word furfur. Hazards identification see toxicological information section 11 medical conditions aggravated by overexposure preexisting disorders involving any target organs mentioned in this msds as being at risk may be aggravated by overexposure to this product overexposure signssymptoms ingestion.
Furfural market by raw material, application industry forecast. Studies in humans and animals show that furfural is readily absorbed and is excreted in the urine. Based on directive 200158ec of the commission of the european communities. Du pont starts the production of adiponitrile for the manufacture of nylon 6. Material safety data sheet ifc, supplier in furfural and. A list of the physicochemical properties of furfural is provided in table 1. H302, h312, h314, h332 see point 15 for explanation. It possesses a faint odor of burning and a bitter taste. At atmospheric pressure, fecl 3 also promoted furfural formation from dxylose better than nacl. Cdc niosh pocket guide to chemical hazards furfural. In the atmosphere, furfural is expected to exist predominately in the vapor phase. Material safety data sheet northwest missouri state. It can be produced from agricultural raw materials containing pentosans and lignocellulosic feedstock.
Increase in awareness regarding the renewable alternatives has compelled manufacturers to increase production of biomassbased chemicals such as furfural to produce additives, resins, and fuels to replace the nonrenewable resources such as petrochemicals. Over the past couple of years, several research groups have described approaches to converting. The american conference of governmental industrial hygienists acgih occupational standard for furfural, or threshold limit value tlv is 2 ppm with a skin notation for concerns for vapor irritation of skin and mucous membranes. Product identifier product name xylene chemical name xylene synonyms xylol, dimethyl benzene, xylenol reach reg no. Traces of water and furfural in this stream might limit the efficiency, however, their presence showed little effects in the furfuralwater separation. Furfural c4h3ocho, also called 2furaldehyde, best known member of the furan family and the source of the other technically important furans. At one instance, when halfshift furfural concentrations averaging. Product and company identification product name 2furaldehyde cat no. Furfuryl and furan derivatives with and without additional sidechain substituents and heteroatoms from chemical group 14 commission regulation ec. Sds of 5methyl furfural, safety data sheets, cas 620020. Show this safety data sheet to the doctor in attendance. Sigmaaldrich is a leading life science and high technology company dedicated to providing highquality, safe and certified flavor ingredients with transparent and easily accessible documentation to customers around the globe. One reagent lane fair lawn, nj 07410 for information in north america. Furfural market by raw material, application industry.
View or download the furfural msds material safety data sheet or sds for 804012 from milliporesigma. Chemicalbook provide chemical industry users with furfural boiling point melting point,furfural density msds formula use,if you also. Production of furfural from xylose at atmospheric pressure by. Ac18100, ac18110, ac18125, ac181100250, ac181102500 synonyms furfural. Furfural serves as a raw material in the preparation of furan, tetrahydrofuran, and tetrahydrofuryl alcohol and in the manufacture of furan resins, fungicides, and such pharmaceuticals as furacin. Destruction by the vapor phase reaction with photochemically produced hydroxyl radicals is expected to be an important process with an estimated halflife of 0. It has a role as a maillard reaction product and a metabolite. National institutes of health public health service u. The information provided on this msds is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. A diverse range of products, all meeting our stringent commitment to quality.
Univar expressly disclaims all express or implied warranties of merchantability and fitness for. Furfural is an aldehyde that is furan with the hydrogen at position 2 substituted by a formyl group. Furfural article about furfural by the free dictionary. Safety data sheet creation date 24apr2009 revision date 18jan2018 revision number 3 1. The yield values were found to be low but not uncommon for furfural processes. Furfural is also known as 2furancarboxaldehyde, furaldehyde, 2furanaldehyde, 2furfuraldehyde, fural, and furfurol. However, due to the low concentration of furfural in the hydrolysate, the conventional methods for furfural recovery are energyintensive and environmentally unfriendly. Hazards identification target organs eyes, respiratory system, skin, liver, kidney, spleen potential health effects. Do not allow into any sewer, on the ground or into any body of water. Background furfural cas no 98011 and ec no 2026277 has a widespread use in cosmetic products as a perfumery ingredient. Along with ethanol, the company can sell the raw furfural or install additional equipment to convert that furfural into derivative chemicals.
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